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Yes Tom, that's what I was talking about. Thanks.Hi Brian, If you are referring to the nickel alloys, eg silveroid, silverode, etc, I've seen some with a patent date of 1884
Tom
The 1864 Robbins & Appleton sales catalog lists "albata" cases for sale. Albata is an earlier name for the same type of nickel-copper-zinc alloy. I have seen exactly one nickel alloy case that looked like it may have been made in that period. The case was empty, but it seems to have been made for a Waltham Model 1857 movement, and it was stamped with an eagle, which strongly suggests early 1860's origin. As I recall, the dust cover carried the name of a Civil War combatant on it. However, nickel cases certainly seem to have been scarce that early. I think exporters were still mostly selling brass cases with gold or silver plating in the low end market at that time.
According to the 1864 R&A catalog, a 2 oz silver case with a "German silver cap" wholesaled for $9.50, and an "albata" case wholesaled for $2.50. This tells me that they were not talking about 2 oz. silver cases with albata dust covers for $2.50, as the price difference with fully silver cases was too great for that to make sense. Also, R&A for some reason made a distinction between albata and "German silver," even though Wikipedia claims that all of the following terms, "Nickel silver, Maillechort, German silver, Argentan, new silver, nickel brass, albata, alpacca, and electrum" supposedly were used to describe nickel alloy cases. (Note: "electrum" is also the name given to naturally occurring mixtures of gold and silver, usually with trace amounts of copper. I have an electrum specimen in my mineral collection.)I doubt that these preceded the full nickel cases, but Waltham 2 oz coin cases often have Albata metal inner covers..
But as mentioned, nickel-copper- ... alloys, in general, were known at least 2 decades before 1884, as evidenced in the 1864 R&A trade sales catalog. Hence, the only supposed novelty suggested in this 1884 announcement is the undisclosed method of thermomechanical treatment. I would have to regard that as an unsubstantiated claim.
I think that may have been Pinchbeck. Alumigold was also around for a while. It is likely that most thought gold was less expensive since you could roll to your hearts content to get down the cost and still have a rather sturdy surface for the life of the wearer.An important question to ask is why the metallurgists could not develop a solid " yellow" base case that would not readily tarnish,. as does brass