Have you tried liver of sulphur (sulphurated potash)? A solution of it is routinely used to darken copper and copper alloys. Sometimes available at craft stores; chemical supply houses will usually carry it, in lump form. I recently bought some at a craft store, "Maid-o'-Metal" brand, along with a bottle of liquid "patina" that adds green patina to brass.
Click Here for an online source.
bangster
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